{"id":330,"date":"2013-10-02T21:49:32","date_gmt":"2013-10-02T21:49:32","guid":{"rendered":"http:\/\/www.studyorgo.com\/blog\/?p=330"},"modified":"2014-02-21T03:22:01","modified_gmt":"2014-02-21T03:22:01","slug":"free-radical-halogenation-module-part-3-stereoselectivity-determining-stereochemistry-of-carbon-centers","status":"publish","type":"post","link":"https:\/\/www.studyorgo.com\/blog\/free-radical-halogenation-module-part-3-stereoselectivity-determining-stereochemistry-of-carbon-centers\/","title":{"rendered":"Free Radical Halogenation Module: Part 3: Stereoselectivity: Determining stereochemistry of carbon centers"},"content":{"rendered":"<p>This is the second part of a multi-part module on Free Radical Halogenation.<\/p>\n<p><a href=\"http:\/\/www.studyorgo.com\/blog\/free-radical-halogenation-module-part-1-the-mechanism\/\">View the first part here: Part 1: The Mechanism<\/a><\/p>\n<p><a href=\"http:\/\/www.studyorgo.com\/blog\/free-radical-halogenation-module-part-2-regioselectivity-determining-the-major-product\/?utm_source=rss&amp;utm_medium=rss&amp;utm_campaign=free-radical-halogenation-module-part-2-regioselectivity-determining-the-major-product\">View the second part here: Part 2: Regioselectivity<\/a><\/p>\n<p>&nbsp;<\/p>\n<p>Radial intermediates (step 2a product) produce an sp2-like hybridization orbital with the lone electron in the vacant 2p orbital, therfore attack of the radical electron on the C-H bond can take place from either side of the molecule.\u00a0 The result will always produce an RACEMIC MIXTURE (or equal amount) of the two enantiomers.<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><a href=\"http:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2013\/08\/Free-Radical-Halogenation-Module-Pic-6.png\"><img loading=\"lazy\" decoding=\"async\" class=\"size-medium wp-image-313 aligncenter\" alt=\"Free Radical Halogenation Module Pic 6\" src=\"http:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2013\/08\/Free-Radical-Halogenation-Module-Pic-6-300x171.png\" width=\"300\" height=\"171\" srcset=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2013\/08\/Free-Radical-Halogenation-Module-Pic-6-300x171.png 300w, https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2013\/08\/Free-Radical-Halogenation-Module-Pic-6.png 475w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p>There are multiple examples of this reaction to review in the\u00a0<a href=\"http:\/\/www.studyorgo.com\/browse-reactions.php?show=all\">StudyOrgo.com Study Mode<\/a>. When ready, test your knowledge in the<a href=\"http:\/\/www.studyorgo.com\/quiz.php\">\u00a0StudyOrgo.com Quiz Mode<\/a>.<\/p>\n<p>Not a member yet?\u00a0<a href=\"https:\/\/www.studyorgo.com\/signup.php\">Sign-Up today!<\/a><\/p>\n<p>&nbsp;<\/p>\n<p>Stay tuned for Part 4:\u00a0Practice Quiz<\/p>\n","protected":false},"excerpt":{"rendered":"<p>This is the second part of a multi-part module on Free Radical Halogenation. View the first part here: Part 1: The Mechanism View the second part here: Part 2: Regioselectivity &nbsp; Radial intermediates (step 2a product) produce an sp2-like hybridization orbital with the lone electron in the vacant 2p orbital, therfore attack of the radical [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-330","post","type-post","status-publish","format-standard","hentry","category-organic-chemistry"],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/posts\/330","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/comments?post=330"}],"version-history":[{"count":3,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/posts\/330\/revisions"}],"predecessor-version":[{"id":340,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/posts\/330\/revisions\/340"}],"wp:attachment":[{"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/media?parent=330"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/categories?post=330"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/tags?post=330"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}