{"id":761,"date":"2016-08-16T02:59:32","date_gmt":"2016-08-16T02:59:32","guid":{"rendered":"https:\/\/www.studyorgo.com\/blog\/?p=761"},"modified":"2016-08-16T03:04:47","modified_gmt":"2016-08-16T03:04:47","slug":"reviewing-molecular-orbitals","status":"publish","type":"post","link":"https:\/\/www.studyorgo.com\/blog\/reviewing-molecular-orbitals\/","title":{"rendered":"Reviewing Molecular Orbitals"},"content":{"rendered":"<p>Gearing up for Organic Chemistry this Fall semester is a smart and efficient way\u00a0for reaching and maintaining a great grade in this class.\u00a0 Most students find the pace of this class very accelerated compared to other courses.\u00a0 This is because while there is a lot of information to learn, it also builds on previous concepts from general chemistry, a course most students want to forget!<\/p>\n<p>But don\u2019t worry!\u00a0 StudyOrgo has you covered.\u00a0 Our Editors have spent years tutoring and teaching Organic Chemistry to students and we have seen all of the pitfalls common to the first few weeks of the semester.\u00a0 Our online platform allows members to learn organic chemistry concepts and mechanisms quickly and the material presented in an easy-to-follow format. Follow along with us and sign up with StudyOrgo today to help prepare you for all of your Organic Chemistry questions.<\/p>\n<p>One of the concepts you will need to have mastered before you \u00a0begin the class is <strong>Hybridized Orbital Theory<\/strong>.<\/p>\n<p>Lets look at\u00a0carbon, the atom this class is about.\u00a0 Recall that it has atomic number 6, which means it has 6 electrons.\u00a0 Remember that the rows, or periods, of the periodic table reflect the outer electron orbital.\u00a0 In the second period, carbon has 4 electrons in its outer orbital.\u00a0 These are the electrons that are available for bonding. \u00a0The carbon atom wants to eventually achieve 8 electrons to fulfill the <strong>Octet Rule, so it needs to make 4 covalent bonds.<\/strong>\u00a0Below is how the electrons are filled in their orbitals. \u00a0Recall that the columns, or groups, of the periodic table reflect the type of electron orbitals present in the atom. \u00a0The red block is the location of\u00a0carbon, which indicates that carbon has 2 s-orbital and 2 p-orbital electrons.<\/p>\n<p><a href=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-762 size-medium\" src=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-1-300x181.png\" alt=\"AO fig 1\" width=\"300\" height=\"181\" srcset=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-1-300x181.png 300w, https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-1-768x462.png 768w, https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-1.png 801w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p>These electrons are arranged in an energy diagram according to their energy, shown below<\/p>\n<p><a href=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-2-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-767 size-medium\" src=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-2-1-300x244.png\" alt=\"AO fig 2\" width=\"300\" height=\"244\" srcset=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-2-1-300x244.png 300w, https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-2-1.png 588w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p>But it we consider the molecular shape of methane (CH4), we will observe it as tetrahedral, where all 4 C-H bonds appear to be equal, so how do the electron energies become equal?<\/p>\n<p>&nbsp;<\/p>\n<p><a href=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/Picture1-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-medium wp-image-770\" src=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/Picture1-1-300x264.png\" alt=\"Picture1\" width=\"300\" height=\"264\" srcset=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/Picture1-1-300x264.png 300w, https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/Picture1-1.png 325w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p>We explain this observation by assuming that the s-orbital and p-orbital electron energies, while different merge into an <strong>sp3 hybridized orbital<\/strong>.\u00a0 In this model, the 2 s-orbial and 2 p-orbital electrons merge into something that resembles a dumbbell.\u00a0 Since all of the orbitals have the same shape and energy, the C-H bonds of methane can be equal and form the observed tetrahedral orientation.\u00a0 There are three types of hybridized orbitals for carbon;<\/p>\n<p><a href=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-4-e1471315765649.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-765\" src=\"https:\/\/www.studyorgo.com\/blog\/wp-content\/uploads\/2016\/08\/AO-fig-4-e1471315765649.png\" alt=\"AO fig 4\" width=\"972\" height=\"659\" \/><\/a><\/p>\n<ul>\n<li><strong>sp3<\/strong> \u2013 which has 4 single (sigma) bonds. The molecular geometry is <strong>tetrahedral<\/strong>.<\/li>\n<li><strong>sp2<\/strong> \u2013 which has 3 single (sigma) bonds and 1 double (1 pi) bond. The molecular geometry is <strong>trigonal planar<\/strong>.<\/li>\n<li><strong>sp<\/strong> \u2013 which has 2 single (sigma) bonds and 1 triple (2 pi) bonds. The molecular geometry is <strong>linear<\/strong>.<\/li>\n<\/ul>\n<p>With a good study plan and help from StudyOrgo, you&#8217;ll have no trouble passing your organic chemistry quizzes and exams this semester. <a href=\"https:\/\/www.studyorgo.com\/signup.php\">\u00a0Sign up today <\/a>for more comprehensive and clear-cut explanations on all of your organic chemistry topics today!<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Gearing up for Organic Chemistry this Fall semester is a smart and efficient way\u00a0for reaching and maintaining a great grade in this class.\u00a0 Most students find the pace of this class very accelerated compared to other courses.\u00a0 This is because while there is a lot of information to learn, it also builds on previous concepts [&hellip;]<\/p>\n","protected":false},"author":7,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-761","post","type-post","status-publish","format-standard","hentry","category-organic-chemistry"],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/posts\/761","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/users\/7"}],"replies":[{"embeddable":true,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/comments?post=761"}],"version-history":[{"count":6,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/posts\/761\/revisions"}],"predecessor-version":[{"id":775,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/posts\/761\/revisions\/775"}],"wp:attachment":[{"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/media?parent=761"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/categories?post=761"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.studyorgo.com\/blog\/wp-json\/wp\/v2\/tags?post=761"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}