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Free Radical Halogenation
Reaction 1 of 116
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- Overall Big Picture: Alkane + Halogen in the presence of heat or light→ Alkyl halide
- Depicted here is free radical bromonation (the halogen here is Br). However, this can also be accomplished with Cl or I .
- Mechanism Hint: There are three steps to the mechanism in this reaction:
- Key Tip: Free radical stability follows carbocation stability:
- allylic > tertiary > secondary > primary > methyl
- Therefore this reaction will want to form the most stable free radical during the propogation step and thus the halogen will appear in the more substituted position. For example, in this reaction, the Br appears on the most substituted carbon in the product.
- Key Comparison:
- Free radical bromonation is a slower reaction and depends on the stability of the free radical intermediate.
- Free radical chloronation is a more rapid reaction and depends not on the stability of the free radical intermediate, but rather on the number of hydrogens present. Therefore, an unreliable mixture of products tends to be formed with free radical chloronation.